Spectroscopy Tutorials B
General data
Course ID:  12001SPEKTBC4  Erasmus code / ISCED:  13.3 / (0531) Chemistry 
Course title:  Spectroscopy Tutorials B  Name in Polish:  Spektroskopia B  ćwiczenia 
Department:  Faculty of Chemistry  
Course groups: 
(in Polish) Przedmioty minimum programowego  zamienniki dla studentów 4go semestru (S1CH) 

ECTS credit allocation (and other scores):  1.50  
Language:  Polish  
Type of course:  obligatory courses 

Prerequisites (description):  A student should have completed courses in mathematics,physics and quantum chemistry. 

Mode:  (in Polish) w sali 

Short description: 
The course is one of the basic courses in Bachelor studies in Chemistry (complementary to the lectures in Spectroscopy B). It is supposed to introduce the students to the methods of quantatitive and qualitative interpretation of the molecular spectra, analysed in terms of molecular symmetry and structure, and to analytical applications of molecular spectroscopy. 

Full description: 
The tutorial is geared towards educating the students in qualitative and quantitative interpretation of the spectra in terms of molecular symmetry and structure and analytical applications of molecular spectroscopy. We will recollect (after having introduced them in the lecture) the quantitative description of the electromagnetic radiation, the relation of peak position and the energy levels of the molecule, the Boltzmann distribution, the relation of the peak intensity and the transition moment and population of the energy levels, and the Doppler effect. The relevant computational problems will be solved. During the following classes the student will be solving problems related to: a) rotational spectroscopy: interpretation of the microwave spectrum and rotational Raman spectrum of twoatomic and simple polyatomic molecules in term of molecular geometric parameters, modelling of spectral intensities in rotational spectrum; b) vibrational spectroscopy: energy levels of harmonic and anharmonic application of group theory in interpretation of vibrational spectra, prediction of the activity of a vibration in IR and Raman spectrum on the basis of group theory, quantitative interpretation of the rotationalvibrational spectra of twoatomic molecules; c) electronic spectra: selection rules in atoms and molecules, application of group theory in interpretation of electronic spectra, vibrational and rotational structure of electronic spectra, determination of dissociation energy from electronic spectra, luminescence spectra. d) electron spin resonance (ESR): resonance condition, prediction of the ESR spectra, determination of the g factor and hyperfine coupling constants from the ESR spectra; e) Nuclear magnetic resonance (NMR): energy levels of magnetic nuclei in external magnetic field, resonance condition, prediction of the form of NMR spectra, calculation of chemical shift and spinspin coupling from the NMR spectra. 

Bibliography: 
Textbooks: P. W. Atkins, Chemia Fizyczna, PWN, Warszawa, 2003. P. W. Atkins, C.A. Trapp, M. P. Cady, C. Giunta Chemia Fizyczna. Zbiór zadań z rozwiązaniami, PWN, Warszawa, 2001. Z. Kęcki, Podstawy spektroskopii molekularnej, PWN, Warszawa, 1992. 

Learning outcomes: 
After completing the tutorial, a student should be able: a) to interpret a spectrum in terms of molecular properties b) to predict the form of a spectrum on the basis of the theory of the given spectroscopic phenomenon c) to use the spectra for quantitative and qualitative analysis 

Assessment methods and assessment criteria: 
Written test, positive mark from 60%. Attendance is obligatory, maximum two absences are allowed. 

Practical placement: 
Does not apply. 
Classes in period "Summer semester 2020/21" (in progress)
Time span:  20210222  20210613 
see course schedule 
Type of class: 
Class, 15 hours more information 

Coordinators:  Magdalena PeculKudelska  
Group instructors:  Magdalena PeculKudelska  
Students list:  (inaccessible to you)  
Examination:  Grading 
Copyright by University of Warsaw.